Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework.

نویسندگان

  • Antigoni Douvali
  • Athanassios C Tsipis
  • Svetlana V Eliseeva
  • Stéphane Petoud
  • Giannis S Papaefstathiou
  • Christos D Malliakas
  • Ioannis Papadas
  • Gerasimos S Armatas
  • Irene Margiolaki
  • Mercouri G Kanatzidis
  • Theodore Lazarides
  • Manolis J Manos
چکیده

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg(2+) metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5 % v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

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عنوان ژورنال:
  • Angewandte Chemie

دوره 54 5  شماره 

صفحات  -

تاریخ انتشار 2015